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Lithium polysilicate is an aqueous solution of lithium oxide and silica featuring a silica to lithium oxide ratio of 4.8. It is commonly used as a concrete hardener and inorganic binder in coatings.
Lithium polysilicate is an inorganic binder useful for coating, surface modification, and polymer reinforcement applications. Unlike polysilicates based on sodium or potassium ions, the lithium ions in lithium polysilicate permit a ratio of 4.8 of silica to lithium oxide. This is one of the highest ratios of silica in polysilicate products on the market.
Lithium polysilicate is typically used in concrete densifiers, where the silica reacts with available calcium hydroxide in the concrete to build density. Unlike other silicate products, the small size of the lithium ion allows for deeper penetration of silica into the concrete, increasing densifier effectivity. Lithium polysilicate is effective in this application at concentrations between 10% and 15%. Upon drying, the excess densifier will become dust that is easily removed without scrubbing or flushing.
Another common application for lithium polysilicate is as a binder for zinc-rich primers and coatings used for corrosion protection in industrial and marine environments. Here, the high ratio of lithium oxide to silica permits greater binding capacity for zinc, yielding films that provide excellent protection against corrosion and chemical attack. Lithium polysilicate may also be used in waterborne masonry paints to form films with good adhesion to masonry and cementitious substrates. It is also used in anticorrosive metal pretreatments to improve the adhesion of coatings applied. Lithium polysilicate has also been used as a safer replacement in formulations that use hexavalent chromium.
Density (g/cm³, lb/gal): 1.19, 9.9
Boiling point (101 kPa), °C (°F): 100 (212)
Melting point, °C (°F): 0 (32)
Vapor pressure (25°C) mmHg: 17.5
pH: 11
Primary Chemistry: Lithium Silicate
Alkaline pH (~11)
Extremely compatible with powdered zinc for zinc-rich primers
Penetrates deeper into concrete than other polysilicate products
Little to no waste upon drying
High ratio of lithium oxide to silicate results in lower levels of water in coatings
Porosity of concrete surfaces that leads to damage caused by exposure to moisture
Low density of highly porous surfaces
Inefficient application of concrete treatments caused by sodium and potassium silicate
Poor chemical and abrasion resistance in coatings and primers
Zinc-rich primers
Coatings for masonry and cementitious surfaces
Concrete densification
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